A fluorinated dendritic TsDPEN-Ru(II) catalyst for asymmetric transfer hydrogenation of prochiral ketones in aqueous media.

نویسندگان

  • Weiwei Wang
  • Quanrui Wang
چکیده

The fluorinated dendritic chiral mono-N-tosylated 1,2-diphenylethlenediamine, FTsDPEN, has been synthesized and applied in the ruthenium(ii) complex-catalyzed asymmetric transfer hydrogenation of prochiral ketones in aqueous media.

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منابع مشابه

A fluorinated dendritic TsDPEN-Ru(II) catalyst for asymmetric transfer hydrogenation of prochiral ketones in aqueous mediaw

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In this account, we describe the design, synthesis and applications of tethered versions of the Ru(II)/N-tosyl-1,2-diphenylethylene-1,2-diamine (TsDPEN) class of catalyst that are commonly used for asymmetric transfer hydrogenation and asymmetric hydrogenation of ketones and imines. The review covers key aspects of the reaction mechanisms and examples of applications, including industrial appli...

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عنوان ژورنال:
  • Chemical communications

دوره 46 25  شماره 

صفحات  -

تاریخ انتشار 2010